Singer/songwriter Van Hunt lets flow the kind of neo-soul music that prompts candlelit smooch sessions and the wearing of edible underwear, so his pairing with quirky, folk-pop songstress Jesca Hoop is a surprising and lovely mismatch. The Grammy-winning Hunt just released his third album, Popular, and has toured with boldfaced headliners like Alicia Keys. Hoop, meanwhile, was employed as a nanny by Tom Waits and his wife before ending up a Morning Becomes Eclectic darling in recent months; tonight, armed with last year's Kismet, she primes the Temple Bar for Hunt's smooveness.